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Signature of Chemical Exchange in 2D vibrational spectroscopy; Simulations based on the Stochastic Liouville Equations

Wei Zhuang, Tomoyuki Hayashi, Shaul Mukamel, František Šanda, and Thomas la Cour Jansen

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Abstract

The stochastic Liouville equations are employed to investigate the combined signatures in coherent vibrational spectroscopy of chemical exchange and spectral diffusion in molecular complexes and of hydrogen bonding fluctuations in water.

© 2006 Optical Society of America

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