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  • International Quantum Electronics Conference
  • OSA Technical Digest (Optica Publishing Group, 1984),
  • paper ThDD4

Laser Photoacoustic Spectroscopy and Detection of Intramolecular Vibrational Energy Redistribution and Unimolecular Reaction Processes

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Abstract

Formyl fluoride (HFCO) is a model unimolecular chemical reactant that is known to form HF + CO reaction products owing to both photon activation1 (in the UV and vacuum-UV spectral regions) and thermal activation.2 In both cases,3 rovibronic line broadening of the reactant may accompany the reaction process.

© 1984 Optical Society of America

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