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Surface Enhanced 2D-IR spectroscopy of gold nanoparticle capping layers

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Abstract

2D-IR spectroscopy is used to quantify gold nanoparticle infrared surface enhancement. Changes in 2D lineshapes and the appearance of surface group cross peaks demonstrate that 2D-IR offers a unique sensitivity to nanoparticle cappant structure/dynamics.

© 2012 Optical Society of America

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