Abstract
Here we present our first results on the fs to ps relaxations in a series of square-planar d8 metal mixed-ligand dithiolene complexes, investigated with fs time resolved broadband transient absorption spectroscopy. In particular we studied two isoelectronic series (Ni, Pd, Pt) of two homologous complexes to clarify the role of the central atom, the ligands and the solvent. A common photocycle is found with the unexpected involvement of lower lying triplet states. In addition an unusually strong modulation of the electronic dynamics on the time scale of solvation response function is observed
© 2012 Optical Society of America
PDF ArticleMore Like This
F. Araoka and T. Kobayashi
TuG17 International Conference on Ultrafast Phenomena (UP) 2006
Hyo Soon Eom, Cheon Min Kim, Sae Chae Jeoung, and Dongho Kim
FE.54 International Conference on Ultrafast Phenomena (UP) 1996
Zhi Li, Song Yue, Jianjun Chen, and Qihuang Gong
JThE11 Quantum Electronics and Laser Science Conference (CLEO:FS) 2010