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Application of time-resolved Fourier-transform spectroscopy to dissociation dynamics

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Abstract

Following photodissociation of vinyl halides C2H3X at 193 nm, bimodal rotational distributions of HX are observed in all cases with a step-scan spectrometer. Observed low-J and high-J components correspond to four-center and three-center HX-elimination channels.

© 2001 Optical Society of America

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