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Conferences > CLEO > 1983 > WJ > WJ1

Subpicosecond time-resolved multiphotonionization: excited state dynamics of cis-stilbene in collision-free conditions

B. I. Greene and R. C. Farrow

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Abstract

We report the results of a novel subpicosecond measurement performed on cis-stilbene in the vapor phase. As will be described, we extended a well- known pulsed laser technique1,2 into the 10-3-sec time regime and chose to focus renewed scientific attention on the dynamics of stilbene photoisomerization. We believe this measurement will establish the technique of gas-phase multiphoton ionization as a viable and potentially powerful subpicosecond probe of intramolecular dynamics.

© 1983 Optical Society of America

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