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Improved laser technique for high-sensitivity atomic absorption spectroscopy in flames

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Abstract

Atomic absorption spectroscopy has traditionally been used to give moderately sensitive detection of trace atomic species aspirated from a test solution into a flame. Laser absorption methods have recently been used to detect major molecular species such as OH radicals.1 Such methods generally require a minimum of 5-10% absorption. We report here on the application of frequency modulation (FM) spectroscopy2 to improve significantly the sensitivity of laser absorption measurements in a flame environment.

© 1983 Optical Society of America

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