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Conferences > CLEO > 1983 > THI > THI2

Excimer laser photodissociation of rare-gas dimer ions; diagnostic technique for examining rare-gas halide dimer and trimer formation kinetics

A. W. Mccown, M. N. Ediger, S. M. Stazak, and J. G. Eden

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Abstract

The formation kinetics of rare gas-halide dimer and trimer molecules (RgX and Rg2X) have previously been Investigated using discharge and E-beam techniques.1 While the dominant RgX* formation mechanisms are ion-ion recombination and the harpoon reaction, Rg2X* formation has been solely attributed to three-body quenching of RgX*. However, due to the large number of excited and ionic species created in discharge and e-beam excitations, it is difficult to measure accurately rate constants involved in excimer production.

© 1983 Optical Society of America

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