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Infrared laser-induced photoisomerization of HONO in solid H2

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Abstract

In 1960 Baldeschwieler and Pimentel1 reported that HONO (nitrous acid) isolated in solid N2 under- went an IR photoisomerization with light in the 3800-4000-cm-1 range. Hall and Pimentel2 studied the isomerization using a broadband source and filters. They determined the isomerization rates using a simple first-order kinetic model and reported high quantum yields (of the order of 1).

© 1981 Optical Society of America

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